It’s particularly useful in sunscreen as it has impressive UV resistance and helps block the sun’s UVA and UVB rays from reaching your skin (6Trusted Source).
≤0.3
Dr Peter Dingle (BEd, BSc, PhD)
The lack of clear regulations and controls explains that P25TiO2NPs are still found in many of the commercialized sunscreens in the market. Some of them are coated to reduce the photoactivity of the anatase form, which is known to be responsible for tissue damage, but not enough studies were made on these coated forms. The anatase photoactivity could trigger the production of reactive oxygen species (ROS) generation, as it was stated before. The ROS are chemically reactive species containing oxygen, such as peroxides, superoxide, hydroxyl radical, and singlet oxygen. They are regularly produced in the biological milieu and counterbalanced by physiological antioxidant defense mechanisms. However, an abrupt increase of ROS may result in non-reversible damage to the skin cells. The effects of coated and uncoated P25TiO2NPs need therefore to be studied, and articles on this topic present different conclusions. [11], [12], [13] Recent literature on this topic found that TiO2NPs inhalation provokes serious genotoxicity and DNA damage [14], [15], [16], [17]. On the other hand, some studies in rats have reported no significant harm to genetic material [18], [19], [20], [21], [22].
Operating temperatures for engine oil seals (see Fig. 14.11 and cross-section of lip seal with garter spring in Fig. 14.22) vary widely, depending on engine design and location within the engine. Typically, the rear crankshaft seal is subjected to much higher temperatures than the front seal. Oil sump temperatures vary considerably, depending on provisions for oil cooling. This allows use of hydrogenated nitrile (HNBR), silicone, or acrylic elastomers for some seals in relatively low-temperature environments (120–140°C or 250–284°F). Standard fluoroelastomers (FKM), bisphenol-cured VDF/HFP/TFE terpolymers with 68–69% fluorine content, perform well in oil service up to about 160°C (320°F). More resistant fluoroelastomers are necessary for reliable long-term performance in more severe environments.
Notes
1) ISO: International Organization for Standardization
2) 2) JIS: Japanese Industrial Standard
When there is a need for rebuilding a cylinder and pump instead of building a new one.
Automotive rubber gaskets are widely used in various vehicle systems for their flexibility, resilience, and sealing properties. These gaskets are employed in applications such as engines, transmissions, and exhaust systems, providing reliable sealing solutions to prevent fluid or gas leakage. The versatility and durability of automotive rubber gaskets make them essential components in maintaining the integrity and efficiency of vehicle systems.
Indeed, when installing this oil seal, the oil sump must be installed using silicone seal. Removal of the old seal and oil sump is necessary, otherwise the oil seal cannot be fitted properly either. If these steps are not followed, leakage is inevitable.
Lift out the rags without dropping dirt into the engine, bores or passages.
Vulcanizates of several fluoroelastomers, listed in Table 14.1, were exposed to a standard 5W-30 engine oil, ASTM Service Fluid 105, for up to 6 weeks at 150°C (302°F).5 The oil was changed weekly, but was not aerated. Retained elongation was measured after exposure for 1, 2, 3, and 6 weeks; data are shown in Fig. 14.3. The results indicate that bisphenol-cured FKM-A500 VDF/HFP copolymer, FKM-B600 VDF/HFP/TFE terpolymer, and peroxide-cured FEPM-7456 TFE/P/VDF terpolymer lost most of their original elongation over the course of the test exposure, indicating considerable additional cross-linking occurred by reaction with amine- and phenol-containing oil additives. The other fluoroelastomers showed better retention of elongation, being much less susceptible to additional crosslinking. Note that FEPM-7456 contains a high level of VDF (about 30%), while FEPM-7506 contains a relatively low VDF level (10–15%) to serve as cure site for bisphenol curing. The other FEPM types contain no VDF.
The spring shown in the figure is known as a garter spring, and it maintains tension on the sealing lip of the seal. Garter springs are closed coil springs used in the form of a ring, the ends of which are connected together as shown in Figure 2.10.
