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  • Import and export data

    According to customs data, the cumulative import volume of titanium dioxide from January to November 2022 is about 116200 tons, a decrease of 34.06% over the same period last year, and the import volume is about 60000 tons; It is estimated that the annual import volume will be 120000 tons, about 70000 tons less than last year. The domestic market demand is weak, and the import of titanium dioxide in China has declined significantly. The new capacity of domestic chlorinated titanium dioxide increased, and the high-end titanium dioxide imported from abroad decreased accordingly.

    According to customs data, from January to November 2022, the total export volume of titanium dioxide was about 1279100 tons, an increase of 8.58% over the same period last year, and the export volume increased by about 101100 tons. The export market maintained a stable and rising trend, and the annual export volume is expected to be 1.38 million tons. The export situation in the first half of the year was better than that in the second half, and the overall export market maintained an increasing trend.

    Capacity output

    According to public data, the cumulative output of titanium dioxide from January to November 2022 is about 3.5755 million tons, up 3% over the same period of last year, with an increase of about 96400 tons, and the annual output is expected to be 3.9 million tons. The enterprises that have increased the output of titanium dioxide this year are mainly, an increase of 11%

    The output growth rate was 2%. This year, the newly launched enterprises CITIC Titanium Industry, Yibin Tianyuan, Shengwei Fuquan and Xianghai Titanium Industry had a significant increase in output compared with last year, and the output of more than 20 small and medium-sized enterprises in the market decreased by different degrees compared with last year.

    Downstream terminal

    From January to November, the national real estate development investment was 12386.3 billion yuan, down 9.8% year on year; Among them, the residential investment was 9401.6 billion yuan, down 9.2%.

    From January to November, the housing construction area of real estate development enterprises was 8968.57 million square meters, down 6.5% year on year. Among them, the residential construction area was 6339.16 million square meters, down 6.7%. The newly started housing area was 1116.32 million square meters, down 38.9%. Among them, the newly started residential area was 817.34 million square meters, down 39.5%. The completed housing area was 557.09 million square meters, down 19.0%. Among them, the completed residential area was 404.42 million square meters, down 18.4%.

    From January to November, the sales area of commercial housing was 1212.5 million square meters, down 23.3% year on year, including the residential sales area, down 26.2%. The sales volume of commercial housing was 11864.8 billion yuan, down 26.6%, of which the sales volume of residential housing was down 28.4%.

    At the end of November, the area of commercial housing for sale was 55.203 million square meters, with a year-on-year growth of 10.0%. Among them, the residential area for sale increased by 18.0%.

    From January to November, the paid in capital of real estate development enterprises was 13631.3 billion yuan, down 25.7% year on year. Among them, domestic loans amounted to 1582.3 billion yuan, down 26.9%; The utilization of foreign capital was 6.6 billion yuan, down 26.6%; Self raised funds amounted to 4899.4 billion yuan, down 17.5%; Deposit and advance receipts amounted to 4460.1 billion yuan, down 33.6%; Personal mortgage loans reached 2187 billion yuan, down 26.2%.

    On the whole, affected by the economic pressure this year, the sales volume of real estate has gradually declined this year, and the national infrastructure investment index has also continued to decline. The demand growth of the downstream coating industry will slow down. At present, the purchase restriction policy of real estate has been cancelled, and in November, a trillion yuan of large state-owned banks rushed to help the real estate industry, which is good for the current market to a certain extent.

    3. Future market forecast

    According to the titanium dioxide analysts from the Chemical Branch of the Business Cooperative, the market price of titanium dioxide will fall sharply in 2022. Affected by the economic situation, the domestic market will be light, but the export market will remain good. The introduction of various favorable policies for real estate before the year will benefit the titanium dioxide market to some extent. It is expected that the titanium dioxide market will mainly maintain stable operation in the short term.
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    2: Clarification mechanism of coagulant

    Chemical coagulation is a process in which chemical agents (coagulants) are added to water treatment to make colloidal dispersion system destabilize and agglomerate. In the coagulation process, small suspended particles and colloidal impurities are aggregated into larger solid particles to separate particulate impurities from water, which is called coagulation clarification.

    After adding coagulant into water, colloidal particles and other small particles can be polymerized into larger flocs through the comprehensive action of mixing, coagulation and flocculation. The whole process of coagulation and flocculation is called coagulation.

    (1) Destabilization and condensation of colloids

    Adding electrolyte to water can compress the electric double layer and destabilize the colloid. The main mechanism is that the electric double layer of colloidal particles in water is compressed or neutralized by adding aluminum salt or iron salt coagulant. The coagulant and raw water are mixed rapidly and evenly, and a series of chemical reactions are produced to destabilize. This process takes a short time, generally about 1 min. Some cationic polymers can also play a role in the destabilization and condensation of colloids in water. These polymers have a long chain structure and positive charge in water. Their destabilization and condensation of colloids in water is due to the interaction of van der Waals force adsorption and electrostatic attraction.

    (2) Flocculation and formation of floc (alum)

    The particle size of the initial flocculate formed by colloid destabilization and coagulation in water is generally more than 1 m. at this time, Brownian motion can no longer push them to collide and form larger particles. In order to make the initial flocs collide with each other to form large flocs, it is necessary to input additional energy into the water to produce a velocity gradient. Sometimes it is necessary to add organic polymer flocculant into water, and the adsorption bridging effect of long chain molecules of flocculant is used to improve the probability of collision and adhesion. Flocculation efficiency usually increases with the increase of flocculate concentration and flocculation time.

    Compared with polyaluminum chloride, polyaluminum chloride has the advantages of high density, fast settling speed and wide pH adaptability; the coagulation effect is less affected by temperature than that of polyaluminum sulfate; however, when adding ferric salt, it should be noted that when the equipment is not in normal operation, the iron ions will make the effluent color, and may pollute the subsequent desalination equipment.

    ...

    Lithopone was discovered in the 1870s by DuPont. It was manufactured by Krebs Pigments and Chemical Company and other companies. The material came in different seals, which varied in the content of zinc sulfide. Gold seal and Bronze seals contain 40-50% zinc sulfide, offering more hiding power and strength. Although its popularity peaked around 1920, approximately 223,352 tons were produced in 1990. It is mainly used in paints, putty, and in plastics.

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    First, the ammonia leaching method is used as a technical means for the effective treatment of acid leaching slag, and the nano nitrite powder is prepared under a weak alkaline ( Ή 8 8.5 to 10) ammonia environment. In an alkaline environment, some metal impurities such as The solubility of Ca, Mg, Fe and Al hydroxides is low, and the impurities entering the final immersion liquid in the selective leaching of ammonia-ammonium sulfate are reduced, thereby ensuring the quality of the product; the traditional acid method for preparing lithopone is because of the zinc calcination. In the roasting and reduction process of the alkalized alkali, the elemental sulfur and sulfite are more or less produced, and the prepared white powder has a yellowish color, and the metathesis reaction of the patent is carried out in an ammonia solution (alkaline). The final product obtained is sulfate, which is quickly and thoroughly added by desulfurization through 3⁄40 2 , and the whiteness of the product can be ensured without high temperature calcination; the equipment requirement is lower than that of sulfuric acid leaching, and the ordinary steel leaching tank can complete the leaching; The environmental pollution problem of acid leaching residue, especially effectively solves the environmental pollution of heavy metals such as zinc, copper, lead, cadmium and arsenic in acid leaching residue and the influence of acid ions on the storage environment. Realize the recycling of high-value metal zinc in acid leaching slag, realize the acidity improvement of soil and have the comprehensive advantages of low cost, energy saving and environmental protection.

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