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The author thanks Marco Leona, Scientist-in-Charge of the Department of Scientific Research at the Metropolitan Museum of Art for conducting fluorescence spectrometry on Wheel of Fortune and a valuable discussion of the research, as well as Silvia Centeno, Research Scientist at the Metropolitan Museum of Art, who performed Raman analysis on the watercolors and also contributed her insight. The phenomenon of the phosphorescing lithopone was originally discovered during the author's fellowship in the Sherman Fairchild Center for the Conservation of Works on Paper, funded by the Andrew W. Mellon Foundation. The author thanks all her colleagues for their ideas and support during the research of this paper, and special thanks to Rachel Mustalish for her assistance in editing this work.

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X-ray fluorescence spectroscopy (XRF) is a non-destructive technique that can be used to determine barium in TiO2determination of barium as tio2 factory. This method involves bombarding the sample with X-rays and measuring the resulting fluorescence spectrum. XRF offers fast analysis times and requires minimal sample preparation, making it suitable for on-site testing. However, its accuracy may be affected by matrix effects and interference from other elements.

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