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One common method to determine sulfate as TiO2 involves gravimetric analysis. In this technique, a sample containing sulfate is treated with barium chloride, resulting in the precipitation of barium sulfate. The precipitate is then filtered, dried, and weighed. The weight of the barium sulfate precipitate correlates directly with the amount of sulfate originally present in the sample. To express this as TiO2, a conversion factor based on stoichiometry is applied. This method, while straightforward, can be time-consuming and subject to errors in filtration and drying.

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Lithopone, also called zinc-barium white, is a very stable network molecular structure formed by the reaction of zinc sulfate and barium sulfide and calcined at high temperature. Lithopone is a white powder that is non-toxic and non-corrosive. It is insoluble in water and does not interact with hydrogen sulfide and alkali. It dissolves with acid and produces hydrogen sulfide gas.

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Should a grade of lithopone be desired higher than the standard grade and another by-productas, for example, a forty-five*per= cent. grade of lithopone and barium chlorid the following process may be pi'acticed,\vhich, however, is quite analogous to the one already 10o described. Aqueous solutions of the ingredients are prepared as before, in these proportions: zinc sulfate, one hundred and sixty-one pounds; zinc chlorid, one hundred and thirty-six pounds, and barium sulfid, three hundred and thirty-eight pounds. Upon mixing these several solutions the lithopone will at once be precipitated in accordance with the following reaction:

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In conclusion, finding reliable suppliers for barium sulfate is essential for businesses that rely on this mineral for their operations. By requesting quotations from multiple suppliers and considering factors such as price, quality, and reliability, you can make an informed decision and choose the best supplier for your needs. Remember to do thorough research and read reviews before making a decision to ensure that you are getting the best value for your money.

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