titanium oxide and 2 per cent' sulphuric acidand 63 per cent water, are slowly added to a solution containing 1050 pounds of barium sulphide, held in a large cylindrical tank, provided with a rotary agitation :capable of producing rapid agitation. The mass isthus v rapidly agitated, and the 2 per cent of sulphuric acid contained in the titanium acid cake reacts with a small portion of the barium sulphide. This reaction may be represented by the following equation TiO H 80 The free sulphuric acid of the titanium acid cake is neutralized by thebarium sul-' phide solution, forming barium sulphate and hydrogen sulphide, as indicated by the above equation. As the sulphuric acid is present only in a small percentage, the major porltiion of the barium sulphide remains as suc very fine colloidal suspension. The barium sulphate produced is also very fine, and the presence of this. very fine barium sulphate in suspension, and also of the very fine colloidal titanium oxide, is believed to be the explanation of the great improvement in the properties of the finished lithopone.

tion of the precipitate, the mass is filter pressed, dried, muflled and processed in the on the market, in that the {covering capacity of the pigment is greatly increased, as well The titanium oxide is peptized or held in as its fastness to light, and ease of working in oils. It is also superior to the so called double strength lithopone made by doubling the zinc sulphide conent, in that it is very neutral to acid vehicles. It is also far superior to other titanium compounds on the market, inasmuch as greater opacities are obtained with a relatively small amount of titanium oxide, than has heretofore been obtained with far greater proportions of titanium oxide, thereby effecting a considerable economy over that of other similar products containing'titanium oxide.