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In a preferred technical solution, 3⁄40 2 is added to the Lide powder emulsion of the metathesis reaction step, and the mass fraction of 3⁄40 2 added is 10 to 33%, and the lithopone emulsion is desulfurized (mainly hydrosulfate ion or Elemental sulfur), slowly added 3⁄40 2 until the lithopone emulsion is colorless and transparent. The obtained sulfate ion can be recycled and reused in the production process. The chemical reaction equation is: 43⁄40 2 + HS— + OH— → SO/— + 5H 2 0

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Both P25TiO2NPs (with or without vitamin B2) were not found beyond the epidermis in 99% of the analyzed TEM images (Fig. 8). This is coherent with previous findings showing that nanoparticles greater than 50 nm can not penetrate the skin, even in vivo models with movement, stretching, and friction [54]. However, in one of the zones, a few nanoparticles were observed inside a hair follicle. This could be due to the follicle exposure after the localized rupture of this physical barrier when rats were shaved in order to clean the area for cream topical administration. This finding suggests that nanoparticle-based sunscreen should not be applied on recently shaved or harmed skin, in order to avoid nanoparticle skin penetration.

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 2) Purification: Add ammonium persulfate to the final immersion solution for one-time oxidation and iron removal, and add activated carbon to adsorb arsenic and iron co-precipitation to achieve the purpose of removing arsenic. Add the polyacrylamide coagulant to separate and filter before separation. The sulfide solution is added to the solution to remove sulfur, and the separated filtrate obtained by the separation is replaced with zinc powder to remove the remaining impurities to obtain a zinc sulfate ammonia complex liquid, which is used in the next step;

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