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This article discusses the discovery of phosphorescent lithopone on watercolor drawings by American artist John La Farge dated between 1890 and 1905 and the history of lithopone in the pigment industry in the late 19th and early 20th centuries. Despite having many desirable qualities for use in white watercolor or oil paints, the development of lithopone as an artists’ pigment was hampered by its tendency to darken in sunlight. Its availability to, and adoption by, artists remain unclear, as colormen's trade catalogs were generally not explicit in describing white pigments as containing lithopone. Further, lithopone may be mistaken for lead white during visual examination and its short-lived phosphorescence can be easily missed by the uninformed observer. Phosphorescent lithopone has been documented on only one other work-to-date: a watercolor by Van Gogh. In addition to the history of lithopone's manufacture, the article details the mechanism for its phosphorescence and its identification aided by Raman spectroscopy and spectrofluorimetry.

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The Microbar Titanium Dioxide Factory is more than just a manufacturing plant; it is a testament to human ingenuity and the power of technology in shaping our future. Its operations serve as a model for the industry, demonstrating how advanced materials can be produced responsibly and sustainably while driving progress in diverse sectors. As we move towards a more technologically advanced and environmentally conscious society, the Microbar factory's role in the production of titanium dioxide will continue to be pivotal, shaping the world one micro particle at a time.

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In conclusion, the determination of sulfate as TiO2 is a specialized field requiring careful selection of analytical methods. Whether through classical gravimetric analysis, titrimetric procedures, or modern instrumental techniques, each method presents its own set of challenges and benefits. Accuracy, precision, and the context of analysis guide the choice of methodology in ensuring that TiO2 meets the desired specifications for various applications. As science progresses, so too does our ability to measure and control the quality of materials like TiO2, ensuring their safe and effective use across industries.

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