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This article discusses the discovery of phosphorescent lithopone on watercolor drawings by American artist John La Farge dated between 1890 and 1905 and the history of lithopone in the pigment industry in the late 19th and early 20th centuries. Despite having many desirable qualities for use in white watercolor or oil paints, the development of lithopone as an artists' pigment was hampered by its tendency to darken in sunlight. Its availability to, and adoption by, artists remain unclear, as colormen's trade catalogs were generally not explicit in describing white pigments as containing lithopone. Further, lithopone may be mistaken for lead white during visual examination and its short-lived phosphorescence can be easily missed by the uninformed observer. Phosphorescent lithopone has been documented on only one other work-to-date: a watercolor by Van Gogh. In addition to the history of lithopone's manufacture, the article details the mechanism for its phosphorescence and its identification aided by Raman spectroscopy and spectrofluorimetry.

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The global market for rutile titanium dioxide is competitive, with leading manufacturers continuously striving to improve their production processes and product qualityrutile titanium dioxide manufacturers. Innovations such as nanotechnology have allowed for the creation of nano-sized titanium dioxide particles, enhancing the pigment's performance in terms of opacity, strength, and durability. Moreover, environmental concerns have prompted manufacturers to develop more sustainable production practices, including the use of cleaner technologies and waste reduction strategies.

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Titanium dioxide is primarily used as a pigment in oil-based paints and coatings. Its high opacity and ability to provide superior whiteness and brightness make it an ideal choice for enhancing the appearance of pipelines, storage tanks, and machinery in oil refineries. These facilities often operate in harsh conditions, and the durability and weather resistance offered by TiO2-coated surfaces ensure longevity and minimal maintenance.

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Tronox Limited is another major player in the rutile market, with operations in Australia, South Africa, and the United States. The company's rutile production is used for the manufacture of titanium metal, which is in high demand for its strength, lightness, and corrosion resistance. Tronox Limited is also a leading producer of titanium dioxide pigments, which are used in the production of paints, coatings, and plastics
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rutile market manufacturers.

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