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1. The process for preparing from solution, lithoponeof various grades and a soluble commercial byproduct preferably of sodium, which consists in preparing separate solutions of zinc sulfate and barium'sulfid, which solutions are mixed with each other and with that of a third salt adapted to enter into combination with a freed acid group from the firstnamed salts, the same being brought together in equivalent and calculated amounts to produce and precipitate lithopone of the desired percentage, and leave in solution the soluble by-product, substantially as described.

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, 2. The herein-described process for manufacturing lithopone of various grades and a by-product of sodium hydrosulfid, which consists in preparing separate solutions of zinc sulfate and barium sulfid, which solutions are mixed with each other and with that of sodium bisulfate, all in equivalent and calculated amounts to produce and precipitate the desired grade of lithopone and leave the so dium hydrosulfid in solution, substantially as described.

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