china titanium dioxide is a precipitate

Rutile, the most common form of titanium dioxide, is a reddish-brown pigment with a high refractive index and excellent weathering resistance. It is mainly used in paints, coatings, plastics, and paper industries due to its ability to provide excellent whiteness, opacity, and UV protection. Rutile titanium dioxide is typically produced by the sulfate process, which involves the reaction of titanium ore with sulfuric acid to produce titanium sulfate. The resulting solution is then treated with ammonia to precipitate titanium hydroxide, which is subsequently calcined at high temperatures to obtain rutile titanium dioxide.

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Having thus described the origin and uses of the pigment, we now come to the question, what is lithopone? It is, in short, a chemical compound usually consisting of 30.5 per cent zinc sulphide, 1.5 per cent zinc oxide and 68 per cent barium sulphate, but these proportions vary slightly in the different makes. Lithopone of this composition is sold as the highest grade, either as red seal or green seal, as it best suits the idea of the manufacturer. Many manufacturers, especially in Europe, sell and also export other brands under other seals, containing 24, 20, 18 and as little as 12 per cent of zinc sulphide with very small percentages of zinc oxide, the balance being usually barium sulphate, but sometimes certain portions of China clay or gypsum (calcium sulphate) or whiting (calcium carbonate). Such brands are not a chemical compound, but mechanical mixtures of the chemically compounded lithopone and the admixtures referred to.

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