cas no. 13463-67-7 suppliers

Infrared analysis showed that the characteristics bands for the bare nanoparticles are still exhibited in the vitamins@P25TiO2NPs spectra, such as a wide peak in 450–1028 cm−1 related to the stretching vibration of Ti-O-Ti and other peaks in 1630 cm−1 and 3400 cm−1, which represent the surface OH groups stretching. The IR spectrum of vitaminB2@P25TiO2NPs showed signs of binding between compounds. The OH bending peak (1634 cm−1) corresponding to bare nanoparticles disappeared, and the NH2 bending band characteristic of vitamin B2 appeared (1650 cm−1). The IR spectrum of vitaminC@P25TiO2NPs also showed signs of successful functionalization. Bands at 1075 cm−1; 1120 cm−1; 1141 cm−1 were observed, which are originated by CsingleO-C vibrations present in the vitamin C. The intense band at 1672 cm−1 is attributed to the C = O stretching in the lactone ring while the peak at 1026 cm−1 is ascribed to the stretching vibration Ti-O-C. Wide bands at 3880–3600 cm−1 are related to stretching vibration OH groups, but those disappear in the modified nanoparticles spectrum. These observations confirm the interactions between the P25TiO2NPs and the vitamins [35].

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The refractive index, represented by the letter n, of a material describes how light propagates through and is bent by, that material. The magnitude of the refractive index, depending upon the electronic structure of the molecules, governs to what extent the path of light changes, when entering or leaving a material.

Particles in a matrix, like pigment particles surrounded by the binder system in a coating, ink or plastic, can change the propagation direction of light when the particles and the matrix have a different refractive index. This phenomenon, called scattering, results in both white color (provided that the particles do not absorb visible light) and the hiding power of the coating.

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