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Resumo–Este artigo discute a descoberta de litopônio fosforescente em desenhos de aquarela do artista americano John La Farge datados de entre 1890 e 1905 e a história do litopônio na indústria de pigmento no final do século XIX e início do século XX. Apesar de ter muitas qualidades desejáveis para o uso em aquarela branca ou tintas a óleo, o desenvolvimento do litopônio como um pigmento de artistas foi prejudicado por sua tendência a se escurecer na luz solar. Sua disponibilidade para e uso por parte de artistas ainda não está clara, uma vez que os catálogos comerciais dos vendedores de tintas geralmente não eram explícitos na descrição de pigmentos brancos como algo que contém litopônio. Além disso, o litopônio pode ser confundido com o branco de chumbo durante o exame visual e sua fosforescência de curta duração pode ser facilmente perdida pelo observador desinformado. O litopônio fosforescente foi documentado em apenas um outro trabalho até hoje: uma aquarela de Van Gogh. Além da história da manufatura do litopônio, o artigo detalha o mecanismo para a sua fosforescência e sua identificação auxiliada pela espectroscopia de Raman e espectrofluorimetria.

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 With the development of science and technology, various pigments have emerged. Inorganic pigments are facing serious challenges. Nanomaterials are a new class of materials with mesoscopic dimension developed at the end of the 20th century. They are now developing in a low-dimensional and complex direction. . In recent years, nano-Lide powder has been put into industrial production. The zinc sulphate solution is prepared in the same way as the traditional method. In the organic phase (such as benzene), the production cost is high, the wastewater is difficult to recycle, the organic solvent in the production process and the final immersion. Slag is likely to cause environmental pollution, and its development is severely limited.

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