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Washed with ethanol nZnS-BaS0 4 crystalline cake, washing the filter cake drying cabinet at 105 ° C after drying lh pulverized by atomic absorption detection zinc, barium yield, in order to reach 98.4% based on zinc, barium meter 99%, ZnS mass fraction accounted for 36.6%. The total mass fraction of zinc sulfide and barium sulfate reached 99.22%, and the mass fraction of ZnS accounted for 36.6%. The particle size of barium sulfide is larger than that of zinc sulfide, which is 77 nm and 38 calendars respectively. The indicators of tinting strength and oil absorption exceed the GB/T1707-1995 B311 type.

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This constant high rate of ROS production leads rapidly to extreme macromolecular oxidation, here it is observed in the AOPP and MDA detected after 3 h in samples treated with bare P25TiO2NPs (Fig. 6Fig. 7). Macromolecular oxidation includes, among others, both protein and lipid oxidation. The ROS causes protein oxidation by direct reaction or indirect reactions with secondary by-products of oxidative stress. Protein fragmentation or cross-linkages could be produced after the oxidation of amino acid side chains and protein backbones. These and later dityrosine-containing protein products formed during excessive production of oxidants are known as advanced oxidation protein products (AOPP). They absorb at 340 nm and are used to estimate the damage to structural cell amino acids. Lipid oxidation is detected by the conjugation of oxidized polyunsaturated lipids with thiobarbituric acid, forming a molecule that absorbs light at 532 nm. Polyunsaturated lipids are oxidized as a result of a free-radical-mediated chain of reactions. The most exposed targets are usually membrane lipids. The macromolecular damage could represent a deadly danger if it is too extensive, and this might be the case. Moreover, it could be observed that cellular damage continues further and becomes irrevocable after 6 h and MDA could not be detected. This may be due to the fact that the lipids were completely degraded and cells were no longer viable. Lipids from the cell membrane are the most prone to oxidation. In fact, lipid peroxidation biomarkers are used to screen the oxidative body balance [51]. At the same time, AOPP values are up to 30 times higher for bare nanoparticles in comparison to the functionalized ones.

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In the vast and dynamic landscape of global industry, China has carved out a niche for itself as a leader in manufacturing and production. One such example is found within the realm of lithopone, a vital component used extensively in paints, plastics, and other industrial applications. The quality of Chinese lithopone, often underscored by its consistency and reliability, is a reflection of the nation's commitment to innovation and sustainability.

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Application:
1. Due to its rheological and optical properties, Lithopone offers technical and economic advantages wherever organic and inorganic resin systems need to be relatively highly pigmented for specific applications. Lithopone has therefore traditionally been used in putties, mastics, jointing and sealing compounds, primers, undercoats and marking paints. In powder coatings it is possible to replace TiO2 partially, very economically.

2. The low Mohs' hardness of Lithopone leads to low abrasiveness in comparison with TiO2.

3. Lithopone 30 % (= 30% zinc sulfide share) is proven to be of particular use as a TiO2 Substitute in thermoplastic masterbatches. Even at very high pigment loadings it disperses easily. A masterbatch containing 50 % TiO2 and 25 % Lithopone 30 % DS has the same hiding power as one containing 60 %TiO2. Cost savings are strongly related to the price ratio of Lithopone and TiO2 and the price of for example polyethylene or polypropylene.

4. The Lithopone batch has a much higher extrusion rate too. Furthermore the impact strength of many thermoplastics such as PP and ABS can be noticeably improved by using Lithopone as a TiO2 substitute. Generally spoken, Lithopone can be used at loadings up to 80 % by weight without causing polymer breakdown

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