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Nano-sized TiO2 generally shows low or no acute toxicity in both invertebrates and vertebrates. However, exposure of Daphnia magna to 20 ppm TiO2 for 8 consecutive days was found to cause 40 % mortality. Zhu et al. showed minimal toxicity to D. magna after 48 h exposure, while upon chronic exposure for 21 days, D. magna suffered severe growth retardation and mortality. A significant amount of nano-sized TiO2 was found also accumulated in the body of the animals. Similar findings with coated nano-sized TiO2 (T-Lite™ SF, T-Lite™ SF-S and T-Lite™ MAX; BASF SE) were reported by Wiench et al. Biochemical measurements showed that exposure to TiO2 NPs induces significant concentration-dependent antioxidant enzyme activities in D. magna. Lee et al. showed that 7 and 20 nm-sized TiO2 induced no genotoxic effect in D. magna and in the larva of the aquatic midge Chironomus riparius.

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A steep decline in the prices of titanium dioxide was observed in the second half of 2022 as the erratic energy costs along with rising covid cases affected the market negatively. In addition to this, the decreased offtakes from paints and coating industries, weak economic growth, and strict restrictions imposed to deal with the resurgence of covid cases further aided the declining trajectory of titanium butoxide prices.

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Maintaining consistency and quality during scale-up is one of the most challenging aspects of nano-TiO2 production. The factory must adhere to stringent quality control measures, using advanced analytical techniques like X-ray diffraction (XRD) and transmission electron microscopy (TEM) to ensure the purity and uniformity of the nanoparticles. Additionally, environmental safety and health considerations are paramount, given the potential risks associated with nanomaterials.

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