china lithopone powder lithopone zns 30%
Ref. 18% TiO2
Pure PVB is non-toxic and harmless to human body. In addition, ethyl acetate or alcohol can be used as solvent, so PVB is widely used in printing ink of food containers and plastic packaging in European and American countries.
Storage safety properties
PVB can be stored for two years without affecting its quality as long as it is not in direct contact with water; PVB shall be stored in a dry and cool place and avoid direct sunlight. Heavy pressure shall be avoided during PVB storage.
Solubility
PVB is soluble in alcohol, ketone, ester and other solvents. The solubility of various solvents changes according to the functional group composition of PVB itself. Generally speaking, alcohol solvents are soluble, but methanol is more insoluble for those with high acetal groups; The higher the acetal group, the easier it is to dissolve in ketone solvents and ester solvents;
PVB is easily soluble in cellosolve solvents; PVB is only partially dissolved in aromatic solvents such as xylene and toluene; PVB is insoluble in hydrocarbon solvents.
Viscosity characteristics of PVB solution
The viscosity of PVB solution is greatly affected by the formula of solvent and the type of solvent; Generally speaking, if alcohol is used as solvent, the higher the molecular weight of alcohol, the higher the viscosity of PVB solution;
Aromatic solvents such as xylene and toluene and hydrocarbon solvents can be used as diluents to reduce the viscosity of PVB solution; The effect of PVB chemical composition on viscosity is summarized as follows: under the same solvent and the same content of each base, the higher the degree of polymerization, the higher the solution viscosity; Under the same solvent and the same degree of polymerization, the higher the acetal group or acetate group, the lower the solution viscosity.
Dissolution method of PVB
Where mixed solvents are used, the dissolution step is to first put aromatic solvents (such as xylene, toluene, etc.) or ester solvents (such as n-butyl acetate, ethyl acetate, etc.) into the mixing, slowly put PVB into the mixing, and then add alcohol solvents (such as n-butanol, ethanol, etc.) after PVB is dispersed and expanded,
At this time, the dissolution time can be shortened by heating; Using this dissolution method, the formation of lumpy PVB can be avoided (because the dissolution time will be several times after the formation of lumpy PVB), so the dissolution speed can be accelerated. Generally, the ratio of aromatic and alcohol solvents is 60 / 40 ~ 40 / 60 (weight ratio), and PVB solution with low viscosity can be prepared.
The solvent composition contains 2 ~ 3wt% water, which can improve the hydrogen bonding strength of alcohol solvents and help the solubility of PVB.
Processing properties
Although PVB resin is a thermoplastic, it has little processability before plasticizer is added. Once plasticizer is added, its processability is very easy.
The purpose of general coatings and adhesives is to change the resin characteristics by adding plasticizers to meet the application requirements, such as film softness, reducing the TG point of the resin, reducing the heat sealing temperature, maintaining low-temperature softness, etc.
Compatibility
PVB can be compatible with a variety of resins, such as phenolic resin, epoxy resin, alkyd resin and MELAMINE resin.
B-08sy, b-06sy and b-05sy with high acetal degree can be mixed with nitrocellulose in any proportion. PVB and alkyd resin are partially compatible. General PVB is compatible with low molecular weight epoxy resin, while high molecular weight epoxy resin needs PVB with high acetal degree to be compatible with each other.
Pure PVB is non-toxic and harmless to human body. In addition, ethyl acetate or alcohol can be used as solvent, so PVB is widely used in printing ink of food containers and plastic packaging in European and American countries.
Storage safety properties
PVB can be stored for two years without affecting its quality as long as it is not in direct contact with water; PVB shall be stored in a dry and cool place and avoid direct sunlight. Heavy pressure shall be avoided during PVB storage.
Solubility
PVB is soluble in alcohol, ketone, ester and other solvents. The solubility of various solvents changes according to the functional group composition of PVB itself. Generally speaking, alcohol solvents are soluble, but methanol is more insoluble for those with high acetal groups; The higher the acetal group, the easier it is to dissolve in ketone solvents and ester solvents;
PVB is easily soluble in cellosolve solvents; PVB is only partially dissolved in aromatic solvents such as xylene and toluene; PVB is insoluble in hydrocarbon solvents.
Viscosity characteristics of PVB solution
The viscosity of PVB solution is greatly affected by the formula of solvent and the type of solvent; Generally speaking, if alcohol is used as solvent, the higher the molecular weight of alcohol, the higher the viscosity of PVB solution;
Aromatic solvents such as xylene and toluene and hydrocarbon solvents can be used as diluents to reduce the viscosity of PVB solution; The effect of PVB chemical composition on viscosity is summarized as follows: under the same solvent and the same content of each base, the higher the degree of polymerization, the higher the solution viscosity; Under the same solvent and the same degree of polymerization, the higher the acetal group or acetate group, the lower the solution viscosity.
Dissolution method of PVB
Where mixed solvents are used, the dissolution step is to first put aromatic solvents (such as xylene, toluene, etc.) or ester solvents (such as n-butyl acetate, ethyl acetate, etc.) into the mixing, slowly put PVB into the mixing, and then add alcohol solvents (such as n-butanol, ethanol, etc.) after PVB is dispersed and expanded,
At this time, the dissolution time can be shortened by heating; Using this dissolution method, the formation of lumpy PVB can be avoided (because the dissolution time will be several times after the formation of lumpy PVB), so the dissolution speed can be accelerated. Generally, the ratio of aromatic and alcohol solvents is 60 / 40 ~ 40 / 60 (weight ratio), and PVB solution with low viscosity can be prepared.
The solvent composition contains 2 ~ 3wt% water, which can improve the hydrogen bonding strength of alcohol solvents and help the solubility of PVB.
Processing properties
Although PVB resin is a thermoplastic, it has little processability before plasticizer is added. Once plasticizer is added, its processability is very easy.
The purpose of general coatings and adhesives is to change the resin characteristics by adding plasticizers to meet the application requirements, such as film softness, reducing the TG point of the resin, reducing the heat sealing temperature, maintaining low-temperature softness, etc.
Compatibility
PVB can be compatible with a variety of resins, such as phenolic resin, epoxy resin, alkyd resin and MELAMINE resin.
B-08sy, b-06sy and b-05sy with high acetal degree can be mixed with nitrocellulose in any proportion. PVB and alkyd resin are partially compatible. General PVB is compatible with low molecular weight epoxy resin, while high molecular weight epoxy resin needs PVB with high acetal degree to be compatible with each other.
Price trend
The successful completion of 2022. Looking at the development of Titanium Dioxide market in this year, from the perspective of price, according to the monitoring of bulk commodity data, the price of titanium dioxide will fall in 2022. The average price of domestic titanium dioxide at the beginning of the year was 20733.33 yuan/ton, and the average price at the end of the year was 15933.33 yuan/ton. The price fell by 23.15% during the year.
2. Market analysis
Product quotation
From the perspective of market development in 2022, prices in the first half of the year are basically in a stable stage, with little fluctuation, and prices in the second half of the year are in a rapid decline stage. In November, Longqi sent a letter to raise the price to stabilize the price. At this time, the price of titanium dioxide began to stabilize and stop falling.
In the first quarter, export orders performed well, and the market confidence of titanium dioxide enterprises was good. Before the year, domestic downstream manufacturers mainly hoarded goods moderately before the year. The market rose twice, with a cumulative increase of 1.77% from January to March. The ex factory quotation of domestic rutile titanium dioxide including tax is mostly 20000-22000 yuan/ton; The ex factory quotation of anatase titanium dioxide including tax is between 18000-19500 yuan/ton. After the year, the domestic raw material sulfuric ACID price continued to rise, the enterprise cost was under pressure, and the support was strong. The titanium dioxide market confidence was fair, and the price continued to rise.
In the second quarter, the logistics management and control and the domestic market turnover were light. Affected by logistics control and other factors, transportation is relatively difficult, market supply is shrinking, traders are unstable, and the market price declines with the focus on digesting their own inventory. The cumulative decline from April to June was 3.08%. The ex factory quotation of domestic rutile titanium dioxide including tax is between 19100-22000 yuan/ton; The ex factory quotation of anatase titanium dioxide including tax is between 17800-19000 yuan/ton. The spot market of titanium ore continued to decline, the price of sulfuric acid also continued to decline, and the cost support was weak. At the same time, the performance of the downstream terminal real estate market is poor. Under the superposition of multiple negative factors, the titanium dioxide market fell.
In the third quarter, Longqi guided the price reduction and the titanium dioxide market fell sharply. 7-9 The cumulative decline was 19.85%. The ex factory quotation of domestic rutile titanium dioxide including tax is mostly between 15500-17000 yuan/ton; The quotation of anatase titanium dioxide is between 14500-15500 yuan/ton. Due to the limited power supply and other factors, the titanium dioxide enterprises in southwest China have reduced their production. The market price of raw sulfuric acid fell rapidly, and the cost support was weak. In addition, the domestic titanium dioxide market demand continues to be sluggish, and the manufacturer's inventory pressure is still large.
In the fourth quarter, Dragon Enterprise sent a letter in November to promote stability. The cumulative decline was 2.55% from October 12. The titanium dioxide market is about to enter the off-season, and the demand market for coatings is tepid, especially in the northern market. In November, the group announced that the price would rise, and the prices offered by various manufacturers were flexible, so it was more meaningful to stop the decline. Most domestic rutile titanium dioxide prices are between 15000-17500 yuan/ton; The quotation of anatase titanium dioxide is about 14000-14500 yuan/ton. The price of titanium concentrate in Panxi increased. More than 20 domestic titanium dioxide enterprises sent letters to announce the increase, and the international giants Chemurs and Tronox announced the reduction of titanium dioxide production in the fourth quarter, which also benefited the domestic titanium dioxide market and stabilized the market on the whole.
The successful completion of 2022. Looking at the development of Titanium Dioxide market in this year, from the perspective of price, according to the monitoring of bulk commodity data, the price of titanium dioxide will fall in 2022. The average price of domestic titanium dioxide at the beginning of the year was 20733.33 yuan/ton, and the average price at the end of the year was 15933.33 yuan/ton. The price fell by 23.15% during the year.
2. Market analysis
Product quotation
From the perspective of market development in 2022, prices in the first half of the year are basically in a stable stage, with little fluctuation, and prices in the second half of the year are in a rapid decline stage. In November, Longqi sent a letter to raise the price to stabilize the price. At this time, the price of titanium dioxide began to stabilize and stop falling.
In the first quarter, export orders performed well, and the market confidence of titanium dioxide enterprises was good. Before the year, domestic downstream manufacturers mainly hoarded goods moderately before the year. The market rose twice, with a cumulative increase of 1.77% from January to March. The ex factory quotation of domestic rutile titanium dioxide including tax is mostly 20000-22000 yuan/ton; The ex factory quotation of anatase titanium dioxide including tax is between 18000-19500 yuan/ton. After the year, the domestic raw material sulfuric ACID price continued to rise, the enterprise cost was under pressure, and the support was strong. The titanium dioxide market confidence was fair, and the price continued to rise.
In the second quarter, the logistics management and control and the domestic market turnover were light. Affected by logistics control and other factors, transportation is relatively difficult, market supply is shrinking, traders are unstable, and the market price declines with the focus on digesting their own inventory. The cumulative decline from April to June was 3.08%. The ex factory quotation of domestic rutile titanium dioxide including tax is between 19100-22000 yuan/ton; The ex factory quotation of anatase titanium dioxide including tax is between 17800-19000 yuan/ton. The spot market of titanium ore continued to decline, the price of sulfuric acid also continued to decline, and the cost support was weak. At the same time, the performance of the downstream terminal real estate market is poor. Under the superposition of multiple negative factors, the titanium dioxide market fell.
In the third quarter, Longqi guided the price reduction and the titanium dioxide market fell sharply. 7-9 The cumulative decline was 19.85%. The ex factory quotation of domestic rutile titanium dioxide including tax is mostly between 15500-17000 yuan/ton; The quotation of anatase titanium dioxide is between 14500-15500 yuan/ton. Due to the limited power supply and other factors, the titanium dioxide enterprises in southwest China have reduced their production. The market price of raw sulfuric acid fell rapidly, and the cost support was weak. In addition, the domestic titanium dioxide market demand continues to be sluggish, and the manufacturer's inventory pressure is still large.
In the fourth quarter, Dragon Enterprise sent a letter in November to promote stability. The cumulative decline was 2.55% from October 12. The titanium dioxide market is about to enter the off-season, and the demand market for coatings is tepid, especially in the northern market. In November, the group announced that the price would rise, and the prices offered by various manufacturers were flexible, so it was more meaningful to stop the decline. Most domestic rutile titanium dioxide prices are between 15000-17500 yuan/ton; The quotation of anatase titanium dioxide is about 14000-14500 yuan/ton. The price of titanium concentrate in Panxi increased. More than 20 domestic titanium dioxide enterprises sent letters to announce the increase, and the international giants Chemurs and Tronox announced the reduction of titanium dioxide production in the fourth quarter, which also benefited the domestic titanium dioxide market and stabilized the market on the whole.